Ca element configuration8/12/2023 ![]() The chemistry of calcium is that of a typical heavy alkaline earth metal. ![]() Structure of the polymeric 2+ center in hydrated calcium chloride, illustrating the high coordination number typical for calcium complexes. While calcium is infeasible as a conductor for most terrestrial applications as it reacts quickly with atmospheric oxygen, its use as such in space has been considered. While calcium is a poorer conductor of electricity than copper or aluminium by volume, it is a better conductor by mass than both due to its very low density. Ĭalcium is harder than lead but can be cut with a knife with effort. Its density of 1.55 g/cm 3 is the lowest in its group. It crystallises in the face-centered cubic arrangement like strontium above 450 ☌, it changes to an anisotropic hexagonal close-packed arrangement like magnesium. Physical propertiesĬalcium metal melts at 842 ☌ and boils at 1494 ☌ these values are higher than those for magnesium and strontium, the neighbouring group 2 metals. Nevertheless, beryllium and magnesium differ significantly from the other members of the group in their physical and chemical behaviour: they behave more like aluminium and zinc respectively and have some of the weaker metallic character of the post-transition metals, which is why the traditional definition of the term "alkaline earth metal" excludes them. Ĭalcium, strontium, barium, and radium are always considered to be alkaline earth metals the lighter beryllium and magnesium, also in group 2 of the periodic table, are often included as well. This occurs because of the much greater lattice energy afforded by the more highly charged Ca 2+ cation compared to the hypothetical Ca + cation. Hypothetical univalent salts of calcium would be stable with respect to their elements, but not to disproportionation to the divalent salts and calcium metal, because the enthalpy of formation of MX 2 is much higher than those of the hypothetical MX. Hence, calcium is almost always divalent in its compounds, which are usually ionic. Like the other elements placed in group 2 of the periodic table, calcium has two valence electrons in the outermost s-orbital, which are very easily lost in chemical reactions to form a dipositive ion with the stable electron configuration of a noble gas, in this case argon. A calcium atom has twenty electrons, arranged in the electron configuration 4s 2. Characteristics ClassificationĬalcium is a very ductile silvery metal (sometimes described as pale yellow) whose properties are very similar to the heavier elements in its group, strontium, barium, and radium. Calcium ions outside cells are important for maintaining the potential difference across excitable cell membranes, protein synthesis, and bone formation. As electrolytes, calcium ions (Ca 2+) play a vital role in the physiological and biochemical processes of organisms and cells: in signal transduction pathways where they act as a second messenger in neurotransmitter release from neurons in contraction of all muscle cell types as cofactors in many enzymes and in fertilization. On the other hand, the metal in pure form has few applications due to its high reactivity still, in small quantities it is often used as an alloying component in steelmaking, and sometimes, as a calcium–lead alloy, in making automotive batteries.Ĭalcium is the most abundant metal and the fifth-most abundant element in the human body. Calcium compounds are widely used in many industries: in foods and pharmaceuticals for calcium supplementation, in the paper industry as bleaches, as components in cement and electrical insulators, and in the manufacture of soaps. Pure calcium was isolated in 1808 via electrolysis of its oxide by Humphry Davy, who named the element. Some calcium compounds were known to the ancients, though their chemistry was unknown until the seventeenth century. The name derives from Latin calx " lime", which was obtained from heating limestone. The most common calcium compound on Earth is calcium carbonate, found in limestone and the fossilised remnants of early sea life gypsum, anhydrite, fluorite, and apatite are also sources of calcium. It is the fifth most abundant element in Earth's crust, and the third most abundant metal, after iron and aluminium. ![]() Its physical and chemical properties are most similar to its heavier homologues strontium and barium. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. ![]() Calcium is a chemical element with the symbol Ca and atomic number 20. ![]()
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Prey animals8/12/2023 ![]() ![]() While they may affect abundance in some species, wolves can also play an important role in the environment. In these and other ways, wolves can influence the dynamics of wildlife species across an entire ecosystem, altering predator-prey relationships and even the natural landscape. Studies in other areas have shown that the presence of wolves can reduce coyote populations. They may also compete with other top carnivores such as cougars, bears, and coyotes. Wolves primarily prey on elk, deer, moose, and other ungulates, although they also feed on smaller species such as beaver, mice, squirrels, rabbits, muskrats, marmots, grouse, and even songbirds. ![]() Like bears and cougars, they have few competitors and play a prominent role in any ecosystem they inhabit. Gray wolves are an apex species that occupy a top niche in the natural food chain.
Test takers psiexams8/12/2023 ![]() ![]() Many licensing authorities or sponsors require e-mail contact information for registration. Mailing address – Please provide the address to which you would like your score report or other important information mailed.Į-mail address – Once again for contact purposes, this is often the fastest and most effective means of communication. Number.Ĭontact phone numbers – If there is an unexpected event, we will use these numbers to contact you. Your Social Security, or Licensing Authority/Sponsor issued I.D. At a minimum, the identification must be a valid, government-issued ID that shows your name in the English alphabet, your signature, your photograph. The name used to schedule your appointment must exactly match the name shown on your identification. When you schedule your appointment, you should be prepared to provide any of the following information: What information should I be prepared to provide when I schedule my appointment? Online at Phone by calling our Candidate Service Center 1-80 Site Reliability Engineering (SRE) Practitionerįor most test programs, PSI provides two easy methods to schedule test appointments:.Continuous Delivery Ecosystem Foundation (CDEF).Certified Agile Service Manager (CASM)®.Google Certified Cloud Architect Professional. ![]()
Ushi oni8/12/2023 ![]() ![]() Ushi-oni are also mentioned in Sei Shōnagon's tenth-century diary The Pillow Book, and in the Taiheiki of the fourteenth century. He dedicated its horns to the temple, and they can still be seen to this day. A sign nearby explains that this creature terrorized the area about four-hundred years ago, and was slain by a skilled archer by the name of Yamada Kurando Takakiyo (山田蔵人高清). If youre interested in a oriental campaign, I have some info about Japanese history in the link in my siggy (that 'Homebrew Extended Signature' thread). Coments and constructive critisism greatly appreciated. The data for a Yokai by the name of the Ushi Oni. ![]() ![]() It is a bipedal monster with huge tusks, spurred wrists, and membranes like a flying squirrel. Some random ideas for Japanese or oriental campaigns. Yet another ushi-oni is depicted as a statue on the grounds of the Negoroji temple in Takamatsu, Kagawa Prefecture. This ushi-oni seems to be connected to another monster called the nure-onna, who sometimes appears before an ushi-oni attack and tricks the victim into holding her child, which then becomes stuck to the person's hands and grows heavier in order to hinder escape. It is often depicted with a spider- or crab-like body. It has a sword for a tail, and is thought to drive away evil spirits.Īnother well-known ushi-oni is a massive, brutal sea-monster which lives off the coast of Shimane Prefecture and other places in Western Japan and attacks fishermen. Something like the dragon dancers at a Chinese New Year celebration, this ushi-oni is represented with a huge, multiple-person costume with a cloth body and a carved, painted head held upon a pole. Perhaps the most famous ushi-oni appears as a protective symbol in the Uwajima Ushi-oni Festival, which is held in late July in Uwajima of Ehime Prefecture. There are various kinds of ushi-oni, all of them some sort of monster with a horned, bovine head. The Ushi-Oni (牛鬼?, Ox Oni (demon)), or gyūki, is a creature which appears in the folklore of Japan. ![]() Sketchers escape plan8/12/2023 ![]() ![]() Contracts now often stipulate that partners and vendors must have insurance, liability protection, and cyber defense. This trend is already prevalent in the US, especially in the defense sector. The second approach involves incorporating cybersecurity clauses in vendor contracts. This proactive investment fortifies the most vulnerable links in the chain, ensuring they meet industry standards and contribute to the overall security of the industry. As time passes, vendors will come to recognize the critical nature of these services and assume the associated costs. ![]() ![]() Two methods were proposed: making cyber defense services available to vendors and incorporating cybersecurity requirements in vendor contracts.įirstly, companies can invest in cyber defense services for their principal vendors and incorporate these services into their own comprehensive cybersecurity response plan. However, they must consider the next level – securing their vendors. Even if your company is well-protected, a breach at any link in the chain – like a bunker provider that can’t deliver fuel or a terminal provider that can’t handle your cargo because of a ransomware attack on their systems – could put your operations at risk.Īccording to Bhalotra, companies that have invested in cybersecurity for years and have a trustworthy and tested team are doing a good job. As often stated, “you’re only as strong as the weakest link.” Major cybersecurity incidents, such as the attack on Maersk in 2017, have spotlighted the vulnerability of this sector. In an industry where shippers, carriers, bunker providers, and service providers are intertwined, the risk of cyber-attack extends to the entire supply chain. The interconnected nature of the shipping industry presents unique security challenges. Speaking at the Marine Money Week Conference in New York yesterday, Sameer Bhalotra, Co-founder & CEO of ActZero, a ABS Wavesight partner, emphasized the critical role of cybersecurity measures in vendor contracts and partnership agreements. By John Konrad (gCaptain) In the age of increased cyber threats and vulnerabilities, safeguarding a business extends beyond the perimeter of one’s organization. ![]() Budget rental car receipt8/12/2023 ![]() ![]() ![]() So, rental car companies try to sell you the Collision Damage Waiver (CDW) for an extra fee (usually around $20 per day). According to The Consumerist, some rental companies are charging over $9 per gallon in fees! Make sure you note how much gasoline was in the tank when you picked up the car, and then swing by a gas station on your way to return the vehicle.Ĭollision Damage Waiver: If you get in an accident with your rental car, you can be liable for an extremely high insurance deductible-sometimes thousands of dollars. ![]() (Read more about renting a car under age 25 here.)įuel Charge: Better top off the tank before you return that rental car-otherwise you’ll get hit with a “refueling fee,” which includes the cost of gasoline and a hefty “convenience” charge. Some individual car-rental offices will waive the surcharge, so your best bet is to call around and compare prices before booking. So if you’re under 25, be prepared to pay a daily fee of around $25 (or more) per day. Most places have relaxed the restrictions and now rent to anyone 21 or older-but then slap young drivers with a big surcharge. In the past, most car-rental companies wouldn’t even lease to drivers under 25. Under 25 Penalty: If you’re a quarter of a century old or less, you’ll have to pay big to rent a car. Avoid the charge by picking up your car at a location a bit farther out, but make sure you either find one with a free shuttle or price how much it will cost you to take public transportation or a taxi to a different location-the price difference might not be worth it. Car-rental companies have to pay a “concession fee” to the airport in order to operate near it, and they pass those fees on to the consumer. Read on for the scoop about 10 such hidden fees-and how to avoid the worst of them.Īirport Fee: The most convenient place to pick up a rental car is oftentimes at the airport-but it will cost you. Unlike airfares, for which airlines now have to disclose taxes and fees up front, car-rental companies can still bury extra costs in the fine print, leaving you with serious sticker shock at the checkout desk. ![]() Showtime anytime app not working8/12/2023 ![]() ![]() Uninstalling and restarting your VPN may help you get rid of these bugs, although it would be better to check if the VPN software or app has an update, and download/install that version instead. Most of the time, the issue is with bugs and errors in the VPN. Uninstall and reinstall your VPN software. ![]() You can then use that to access Showtime, as long as it hasn’t been blocked beforehand. Once your server or IP address has been blocked, you can simply connect to a new server and obtain a new IP address. Showtime does not have the capability to block your VPN, although it can block off certain servers from accessing the platform. Once you click accept, your information and data are stored on the computer, including the usage and your original location.Ĭonsequently, if you use a VPN to log into Showtime, the cookies might reveal your actual location, and your connection will then be blocked. Once you log onto a website or streaming platform, you may see a pop-up asking you to accept cookies. To help you get past these issues, we have listed down some of the best troubleshooting tips below: The main reason why Showtime is not working with VPN is that your VPN-provided IP address may have been blocked VPN. Showtime not working with VPN: Quick guide The platform is available worldwide, including Showtime outside US, with the help of ExpressVPN. Showtime is one of the most popular streaming platforms available, providing blockbusters to its audience including shows like The Affair, Dexter, and movies like Everything Everywhere All At Once, and Once Upon a Time in the West. The best solution is to change your IP to US, and this is what ExpressVPN is best at. The main reason why your VPN may stop working while streaming your favorite shows is due to blocked IP addresses. Showtime not working with ExpressVPN is a rare scenario as this VPN is arguably the top Showtime VPN and does not cause any issues while streaming. Fortunately, Showtime is a platform that is completely compatible with ExpressVPN, which is considered the best VPN for Showtime and ensures that the streaming platform works in your region. Showtime not working with VPN is an experience you don’t want to be a part of, especially if you have a list of shows lined up. ![]() Sequential turn signals blazer8/12/2023 ![]() The internal circuitry of the switch back will back feed with the white parking lights on causint the yellow turn to light up but no blink. One other issue i have ran into with full leds is when someone uses switch back leds in the front. When you turn on the parks the bright side lights up and you no longer can see the blink. The only other possible problem is that the led tails could be wired backwards for your truck.i have ran across 3 trucks so far where the wires for park and brake/turn are reversed, so when you plug the 1157 in they seem to blink fine until you turn on the lights. If you swap the two wires in the flasher it would work with any digital flasher. The problem is that led flashers (digital )a re polarity sensitive. I'm going to call United Pacific tomorrow, hopefully they can steer me in the right direction. Maybe there's something special about their flasher? The back of the package says that a United Pacific LED turn signal flasher item #90652 is required (funny how LMC doesn't mention that in their catalog) I looked up that part number on Summit, and it appears to be the same as the flasher I just bought, just a different brand. The flicker feature doesn't appear to be working, maybe that has something to do with the problem? The tail lights are manufactured by United Pacific and feature "sequential flash" and "Brake attention", which apparently means the lights will flicker one time when the brakes are applied. I installed an electronic flasher with a ground wire. I ran a jumper wire straight from the negative lead to the negative battery post, and crimped the running and brake light leads to the proper wires coming straight out of the fuse box. I cut the "socket" end of the tail lights off and hardwired it. I think I've completely ruled out a bad ground at this point. Doesn't look like the tail lights are the problem. ![]() ![]() Installed the replacement tail lights from LMC, same problem. ![]() Virgin mobile cell phone ringtones8/12/2023 ![]() ![]() ![]() Polyphonic Ringtones for Nokia, Sumsung, Motorola and more. New Collection of FREE Ringtones for Your Phone free virgin mobile ringtoneįree Virgin Mobile Ringtone. Available for: Don't know your phone? > - Ringtones, Free Ringtones - BlogHosterRingtones, SMS Ringtones, Polyphonic Ringtones, Logos, Picture MSGS, Free Ringtones for Composer, Colour Backgrounds, Mobile Wallpapers.Free Virgin Mobile Ringtone. mDisney Studios - RingtonesShop for all the latest Disney Mobile ringtones. 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